When you do a DNS lookup, you send a string of characters (e.g. www.domain.com) to your DNS server and you get back an IP address. If in the DNS record of a certain domain (e.g. domain.com) is specified the PTR (pointer) field, you can do the opposite: you can send an IP address and get back the string of characters. This is called reverse DNS (rDNS).
What happens in the WUI image you posted is that all your DNS servers upstream of IPFire (ironically) do not have a PTR record registered with their ISPs (*) and therefore they fail the reverse DNS lookup. However this rarely has consequences in the functionality of a service, with the remarkable exception of a mail server (which basically would get all its email rejected as spam if it does not have a PTR record). In your case everything seems to be working.
(*) the PTR record has to be created by the owner of the IP address, commonly the ISP