You can do so by placing this command in firewall.local, which is sort of a placeholder script for IPFire configurations that cannot be made through the GUI. Please refer to this wiki page for its documentation.
(Disclaimer: Please be careful when editing it, especially when it comes to custom iptables rules. Most “security vulnerabilities” reported back to us eventually turned out to be misconfigurations, or overcredulous custom firewall rules placed in firewall.local.)