Port redirection not working

This one may help:
https://wiki.ipfire.org/configuration/firewall/default-policy#default-firewall-behaviour


This one may help:
https://wiki.ipfire.org/configuration/firewall/options#log-dropped-packets-classified-as-invalid-by-connection-tracking

And this one will help:


EDIT:
and this one for RED to DMZ (orange):